It's a bit strange maybe to say that the Disney Villain from Disney Sleeping Beauty, Maleficent, dressed so much cooler and in fashion and in fact I think it became a referent for many gothic later to be trends and was indeed very cool looking. Maleficent was elegant and way sophisticated with her purple eye shade and green pale skin... And the garment was quite full and impressive.
The Queen of Hearts is one of the weirdest characters in Lewis Carol's "Alice in Wonderland", well I confess Disney's version drives me a bit mad "off with their heads" her temper is furious